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What does it take to be a Transport Correspondent?
In message , at 13:11:36 on
Sat, 23 Apr 2011, Jonathan Morton remarked: It's not just the "Standard". Christian Wolmar, writing in Friday's "Times" states that an HST "has a locomotive at one end". Yerse - but it does have a locomotive at one end... and another at the other end :) -- Roland Perry |
What does it take to be a Transport Correspondent?
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What does it take to be a Transport Correspondent?
On Sat, 23 Apr 2011 11:56:21 +0100
Jeremy Double wrote: If what is being claimed is true - ie that heat is always required to do work then this should be impossible. Heat isn't always required to do work _directly_: hydro-power uses the Exactly. Which was my point. allowing them to do work and move the piston. Almost all of the expansion of the combustion gases is due to the heat liberated by combustion, not due to the increased number of moles of gas (for instance, 1 mole of carbon burning uses 1 mole of oxygen to give 1 mole of carbon dioxide). Remember that most of the gas in the cylinder of an engine is nitrogen from the charge air (air is about 79% nitrogen). That doesn't matter - 1 mole of CO2 at room temperature takes up vastly more volume than 1 mole of liquid a hydrocarbon. If all the reaction did was to heat the air in the cylinder up by 500 hundred degrees and didn't produce any extra gas then very little would happen. The same applies to a steam engine - you don't heat air up and shove hot air into the cylinders, you need to convert a liquid (water) into a gas (steam) to get work out. B2003 |
What does it take to be a Transport Correspondent?
On Apr 21, 1:07*pm, Paul Corfield wrote:
On Wed, 20 Apr 2011 22:40:29 +0100, "Jack Taylor" wrote: The standard of railway-related writing has, for some while, been plummeting steadily lower and we often lambast the BBC for their reporting but today's efforts in the London "Evening Standard" by their Transport Correspondent, Dick Murray, are spectacularly dismal. It is interesting to note that a fair proportion of the comments under today's "6 lines closed over Easter" article are strongly critical of the article and the quality of the journalism. No longer the case - perhaps a moderator's been along? The article in question* did annoy me on Thursday, particularly for its opening sentence: "Huge sections of London's transport system will shut down over the four-day Easter break, it emerged today." Er, no, it didn't emerge on Thursday. It probably emerged weeks, if not months before on http://www.tfl.gov.uk/livetravelnews...r/default.aspx - and also the day previously in TfL's weekly closures email. * http://goo.gl/DXO66 or http://www.thisislondon.co.uk/standa...er-meltdown.do |
What does it take to be a Transport Correspondent?
On Mon, 25 Apr 2011 03:51:02 -0700 (PDT)
martin wrote: "Huge sections of London's transport system will shut down over the four-day Easter break, it emerged today." Er, no, it didn't emerge on Thursday. It probably emerged weeks, if When journos say "it emerged today" what they actually mean is "I just heard about it today when my sub editor told me to look into it". That said, it doesn't make LU's **** poor planned works schedule look any better. B2003 |
What does it take to be a Transport Correspondent?
On Tue, 26 Apr 2011 07:36:39 +0100
Jeremy Double wrote: That doesn't matter - 1 mole of CO2 at room temperature takes up vastly more volume than 1 mole of liquid a hydrocarbon. If all the reaction did was to heat the air in the cylinder up by 500 hundred degrees and didn't produce any extra gas then very little would happen. The same applies to a steam engine - you don't heat air up and shove hot air into the cylinders, you need to convert a liquid (water) into a gas (steam) to get work out. You're talking complete b*******. 1. The volume of one mole CO2 gas is no greater than the volume of the one mole carbon (from either solid or liquid fuel) plus the one mole of oxygen from the air needed to burn it (at the same temperature). Ok, you've got me there. However , it doesn't just produce CO2, it produces steam which is also a gas at those temperatures so you do end up with more gas that you had before since 1 molecule of O2 gives rise to 2 molecules of water. Mind you , it requires heat to convert the water into steam which rather undermines my original argument. Ah well, can't win them all! 3. There is a well-known external-combustion hot-air engine, called the Stirling engine. This was invented by a clergyman, Robert Stirling, father of the 19th century steam locomotive engineers Patrick and James Stirling. It's not as commonly used as the steam engine, but that doesn't mean it's impossible. Since the wikipedia entry on it is huge and I don't have time to read it I'm not going to comment other than to say it can't be that efficient or powerful or we'd all be using them today. I suggest you learn some thermodynamics before making further pronouncements. Actually I think its more my chemistry I need to brush up on. B2003 |
What does it take to be a Transport Correspondent?
On Apr 26, 10:38*am, wrote:
On Tue, 26 Apr 2011 07:36:39 +0100 Jeremy Double wrote: That doesn't matter - 1 mole of CO2 at room temperature takes up vastly more volume than 1 mole of liquid a hydrocarbon. If all the reaction did was to heat the air in the cylinder up by 500 hundred degrees and didn't produce any extra gas then very little would happen. The same applies to a steam engine - you don't heat air up and shove hot air into the cylinders, you need to convert a liquid (water) into a gas (steam) to get work out. You're talking complete b*******. 1. The volume of one mole CO2 gas is no greater than the volume of the one mole carbon (from either solid or liquid fuel) plus the one mole of oxygen from the air needed to burn it (at the same temperature). Ok, you've got me there. However , it doesn't just produce CO2, it produces steam which is also a gas at those temperatures so you do end up with more gas that you had before since 1 molecule of O2 gives rise to 2 molecules of water. Mind you , it requires heat to convert the water into steam which rather undermines my original argument. Right, let's have some numbers here. Consider an Air Standard Otto Cycle. This is a conceptual cycle used for teaching engine thermodynamics, is an approximation to the characteristics of a petrol engine. In this cycle, air is compressed by a certain volume ratio, then heat is added at constant volume (reflecting the fact that combustion is fast compared with the rotating speed of engines), then the resultant mix is expanded by the same volume ratio back to the initial volume, and heat is rejected to restore the initial conditions. There is no change in the chemistry of the working fluid. If we take initial conditions of 288 K (about 15 celsius) and 10^5 Pa (1 bar). Let's let the maximum combustion temperature be 1600 K (to reflect material limitations in our engine), and assume a compression ratio of 10 (ie the ratio of compressed volume to uncompressed volume). Assuming air to have a specific gas constant of 287 kJ/kg K and gamma of 1.4, and idealised compression/expansion, and a cp of 1006 kJ/kg K (reasonable values, you can look them up), then after compression, before combustion, the gas conditions are 24.5x10^5 Pa and 748.5 K. After the heat addition, the conditions are 53.14x10^5 Pa and 1600 K, with the conditions at the end of expansion being 637 K and 2.09x10^5 Pa. The heat addition here is (1600-748.5)*(1006-287)=61.2 kJ/kg (ie per kg of air in the cylinder), producing a pressure increase of 2.14 times. Now, petrol has a lower calorific value of 44.4 MJ/kg (but the values for hydrocarbon fuels are all in the mid 40s, changing between methane and heavy oil makes no big difference), so to get 61.2 kJ we would need to burn 1.3 grammes of petrol for every kg of air. In molar terms, that's 0.011 moles of fuel burning in 34.5 moles of air. If we assume petrol to be octane (C8H18), then the combustion reaction will be C8H18 + 12.5O2 - 8CO2 + 9H2O For 0.011 moles of petrol, we consume 0.011 moles of fuel (the fuel is in the gas phase at this temperature and pressure) and 0.1375 moles of O2 and create 0.187 moles of combustion products. So we have 34.511 moles in the gas phase to start with and 34.5495 moles after combustion. The fact is, the heat release from the fuel is so enormous that the effect of the heat release is several orders of magnitude greater than the effect of changes in mole numbers. 3. There is a well-known external-combustion hot-air engine, called the Stirling engine. *This was invented by a clergyman, Robert Stirling, father of the 19th century steam locomotive engineers Patrick and James Stirling. *It's not as commonly used as the steam engine, but that doesn't mean it's impossible. Since the wikipedia entry on it is huge and I don't have time to read it I'm not going to comment other than to say it can't be that efficient or powerful or we'd all be using them today. Stirling engines can be both efficient and powerful. The problem with them is that they require heat to be transferred from metal to air in the heat addition and rejection stages, and gases generally have poor heat transfer properties, meaning very large heat exchangers. Liquids, on the other hand, have massively better heat transfer characteristics, so heating water in a boiler and cooling it in a condenser gives rise to a much smaller (cheaper) peice of kit, in the form of a steam cycle, for similar performance. Robin |
What does it take to be a Transport Correspondent?
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What does it take to be a Transport Correspondent?
On Tue, 26 Apr 2011 11:22:42 -0700 (PDT)
bob wrote: The fact is, the heat release from the fuel is so enormous that the effect of the heat release is several orders of magnitude greater than the effect of changes in mole numbers. Ok, fine. I'm big enough to admit when I've got it wrong unlike a lot of people on here. B2003 |
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